Direct measurements of latent heat during crystallization and melting of a ugandite and an olivine basalt     

Rebecca A. Lange  Katharine V. Cashman  Alexandra Navrotsky 《Contributions to Mineralogy and Petrology》1994,118(2):169-181

Step-scanning calorimetric measurements using a Setaram HT1500 calorimeter were performed between 800 and 1400°C on two natural samples: a ugandite from the East African rift and an olivine basalt from the western Mexican arc. Our measurements provide the first in-situ quantitative assessment of enthalpy during melting of initially crystalline natural samples. The distribution of latent heat across the liquidus-solidus intervals of the two samples is distinctly different, reflecting significant variation in the sequence and abundance of mineral phases during melting (clinopyroxene and leucite in the ugandite; olivine, clinopyroxene, and plagioclase in the basalt). Our data further indicate that the common assumption of a uniform distribution of latent heat across the liquidus-solidus interval of a magma is a reasonable approximation for the olivine basalt, but is grossly in error for the ugandite. This is due to cotectic precipitation of leucite and clinopyroxene, leading to a large, disproportionate release of latent heat early in the crystallization sequence. The implication for the thermal history of a crystallizing ugandite magma is that therate of heat loss during conductive cooling will unitially be more rapid than the average rate. The net result will be to produce lower magmatic temperatures after a given cooling interval relative to models assuming a uniform release of latent heat. An additional series of scanning calorimetric experiments were performed at variable rates (1,2 and 3°/min) to evaluate the role of kinetics on the distribution of enthalpy during both melting and crystallization of the ugandite and olivine basalt. The results indicate that clinopyroxene is the most important mineral phase in controlling the shapes of the enthalpy profiles during cooling; this is due to its large enthalpy of fusion and its tendency for sluggish nucleation, followed by rapid crystallization at temperatures that vary with cooling rate. The resolution of the calorimeter (in terms of heat detected per unit time) is also important in determining the shapes of theobserved enthalpy profiles during these rapid scans. Estimates based on the observed calorimetric signal associated with melting of olivine, and the lack of a calorimetric signal during melting of leucite, combined with known enthalpies of fusion for the two phases, indicate detection limits of approximately 0.6–1.2 kJ per 5 min increments.  相似文献   

Interaction of cations on octahedral and tetrahedral sites in simple spinels: A comment     

Alexandra Navrotsky 《Physics and Chemistry of Minerals》1984,10(4):192-193

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A thermochemical study of glasses and crystals along the joins silica-calcium aluminate and silica-sodium aluminate     

Alexandra Navrotsky  Gilles Peraudeau  Paul McMillan  Jean-Pierre Coutures 《Geochimica et cosmochimica acta》1982,46(11):2039-2047

Enthalpies of solution in molten 2PbO · B₂O₃ at 985 K are reported for series of glasses xCa_0.5AlO₂-(1?x)SiO₂ (O ≤ x ≤ 0.99) and xNaAlO₂-(1?x)SiO₂ (0 ≤ x ≤ 0.56). The data are compared to values for the corresponding crystalline aluminosilicates and to preliminary data for systems containing KAlO₂ and Mg_0.5AlO₂. The enthalpies of mixing of glasses become more exothermic with increasing basicity of the mono- or divalent oxide. The tendency toward immiscibility on the silica-rich side, indicated by the shape of the heat of mixing curve between x = 0 and x = 0.4, is pronounced in the calcium aluminate system, but not in the sodium aluminate system. The shape of the heat of mixing curve, which is roughly symmetrical about x = 0.5, can be rationalized in terms of glass structure by considering essentially random substitution of Si and Al on a continuous three dimensional tetrahedral framework, with stabilization arising from electrostatic interactions between aluminum and the nonframework cation balancing the destabilizing effects arising from perturbation of the aluminosilicate framework by the nonframework cation. These trends are consistent with the variation of physical properties of aluminosilicate melts.  相似文献   

Derivation Of Refractive Index And Temperature Gradients From Optical Scintillometry To Correct Atmospherically Induced Errors For Highly Precise Geodetic Measurements     

Alexandra I. Weiss  Maria Hennes  Mathias W. Rotach 《Surveys in Geophysics》2001,22(5-6):589-596

Refraction effects of optical beams are generally caused by an inhomogeneous propagation medium and are a major source of systematic errors in the precise optical determination of angles and distances in the atmospheric surface layer. In this contribution a method for deriving vertical temperature and refractive index gradients from optical scintillation is presented. Knowledge of these gradients is required for the compensation of atmospherically induced errors for highly precise terrestrial geodetic measurements, like direct transfer and levelling. The advantage of the present optical method is, that temperature and refractive index gradients can be derived as line-averaged values over the propagation path, which is not possible by meteorological point measurements. Field observations have been carried out with a displaced-beam scintillometer over flat terrain and under different atmospheric conditions in order to verify this method. The experiments show, that this method allows to derive accurate correction values for precise terrestrial geodetic measurements.  相似文献   

Application of Generalized Likelihood Uncertainty Estimation (GLUE) at different temporal scales to reduce the uncertainty level in modelled river flows     

Ragab Ragab  Alexandra Kaelin  Muhammad Afzal  Ioanna Panagea 《水文科学杂志》2020,65(11):1856-1871

ABSTRACT

In this study, the distributed catchment-scale model, DiCaSM, was applied on five catchments across the UK. Given its importance, river flow was selected to study the uncertainty in streamflow prediction using the Generalized Likelihood Uncertainty Estimation (GLUE) methodology at different timescales (daily, monthly, seasonal and annual). The uncertainty analysis showed that the observed river flows were within the predicted bounds/envelope of 5% and 95% percentiles. These predicted river flow bounds contained most of the observed river flows, as expressed by the high containment ratio, CR. In addition to CR, other uncertainty indices – bandwidth B, relative bandwidth RB, degrees of asymmetry S and T, deviation amplitude D, relative deviation amplitude RD and the R factor – also indicated that the predicted river flows have acceptable uncertainty levels. The results show lower uncertainty in predicted river flows when increasing the timescale from daily to monthly to seasonal, with the lowest uncertainty associated with annual flows.  相似文献   

Calculation of effect of cation disorder on silicate spinel phase boundaries     

Alexandra Navrotsky 《Earth and Planetary Science Letters》1977,33(3):437-442

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Footwall mineralization during Late Miocene extension along the West Cycladic Detachment System,Lavrion, Greece     

Alexandra Berger  David A. Schneider  Bernhard Grasemann  Daniel Stockli 《地学学报》2013,25(3):181-191

The West Cycladic Detachment System (WCDS) has been mapped from the western Cycladic islands to Lavrion (mainland Greece), where several top‐to‐SSW low‐angle normal faults at different structural levels are observed. Near the detachment horizon, hydrothermal fluid flow originating from Miocene intrusions lead to high‐temperature carbonate strata‐bound Pb–Ag–Zn ore deposits. Zircon (U–Th)/He cooling ages from the mineralized footwall are 7.1 ± 0.6 to 7.9 ± 0.6 Ma. Carbon‐ and O‐isotope analyses of the carbonate host indicate high water‐to‐rock ratios during brittle deformation‐induced metasomatism, and that this interaction, unrelated to proximity of the intrusions, plays the dominant role in the mineralization. The Late Miocene geology of Lavrion is strikingly similar to Serifos island on the SE termination of the WCDS, both characterized by strong localization of detachment faulting and the interaction of brittle deformation with the injection of fluids related to granitoid intrusions.  相似文献   

Radionuclides and mercury in the salt lakes of the Crimea     

Natalya Mirzoyeva  Larisa Gulina  Sergey Gulin  Olga Plotitsina  Alexandra Stetsuk  Svetlana Arkhipova  Nina Korkishko  Oleg Eremin 《中国海洋湖沼学报》2015,33(6):1413-1425

90 Sr concentrations,resulting from the Chernobyl NPP accident,were determined in the salt lakes of the Crimea(Lakes Kiyatskoe,Kirleutskoe,Kizil-Yar,Bakalskoe and Donuzlav),together with the redistribution between the components of the ecosystems.The content of mercury in the waters of the studied reservoirs was also established.Vertical distributions of natural radionuclide activities( 238 U,232 Th,226 Ra,210 Pb,40 K) and anthropogenic 137 Cs concentrations(as radiotracers) were determined in the bottom sediments of the Koyashskoe salt lake(located in the south-eastern Crimea) to evaluate the longterm dynamics and biogeochemical processes.Radiochemical and chemical analysis was undertaken and radiotracer and statistical methods were applied to the analytical data.The highest concentrations of 90 Sr in the water of Lake Kiyatskoe(350.5 and 98.0 Bq/m 3) and Lake Kirleutskoe(121.3 Bq/m 3) were due to the discharge of the Dnieper water from the North-Crimean Canal.The high content of mercury in Lake Kiyatskoe(363.2 ng/L) and in seawater near Lake Kizil-Yar(364 ng/L) exceeded the maximum permissible concentration(3.5 times the maximum).Natural radionuclides provide the main contribution to the total radioactivity(artificial and natural combined) in the bottom sediments of Lake Koyashskoe.The significant concentration of 210 Pb in the upper layer of bottom sediments of the lake indicates an active inflow of its parent radionuclide—gaseous 222 Rn from the lower layers of the bottom sediment.The average sedimentation rates in Lake Koyashskoe,determined using 210 Pb and 137 Cs data,were 0.117 and 0.109 cm per year,respectively.  相似文献   

Hyperspectral mapping of alteration assemblages within a hydrothermal vug at the Haughton impact structure,Canada          下载免费PDF全文

Rebecca N. Greenberger  John F. Mustard  Gordon R. Osinski  Livio L. Tornabene  Alexandra J. Pontefract  Cassandra L. Marion  Roberta L. Flemming  Janette H. Wilson  Edward A. Cloutis 《Meteoritics & planetary science》2016,51(12):2274-2292

Meteorite impacts on Earth and Mars can generate hydrothermal systems that alter the primary mineralogies of rocks and provide suitable environments for microbial colonization. We investigate a calcite–marcasite‐bearing vug at the ~23 km diameter Haughton impact structure, Devon Island, Nunavut, Canada, using imaging spectroscopy of the outcrop in the field (0.65–1.1 μm) and samples in the laboratory (0.4–2.5 μm), point spectroscopy (0.35–2.5 μm), major element chemistry, and X‐ray diffraction analyses. The mineral assemblages mapped at the outcrop include marcasite; marcasite with minor gypsum and jarosite; fibroferrite and copiapite with minor gypsum and melanterite; gypsum, Fe³⁺ oxides, and jarosite; and calcite, gypsum, clay, microcline, and quartz. Hyperspectral mapping of alteration phases shows spatial patterns that illuminate changes in alteration conditions and formation of specific mineral phases. Marcasite formed from the postimpact hydrothermal system under reducing conditions, while subsequent weathering oxidized the marcasite at low temperatures and water/rock ratios. The acidic fluids resulting from the oxidation collected on flat‐lying portions of the outcrop, precipitating fibroferrite + copiapite. That assemblage then likely dissolved, and the changing chemistry and pH resulting from interaction with the calcite‐rich host rock formed gypsum‐bearing red coatings. These results have implications for understanding water–rock interactions and habitabilities at this site and on Mars.  相似文献   

Temporal Evolution of a Rapidly-Moving Umbral Dot     

Hiroko Watanabe  Alexandra Tritschler  Reizaburo Kitai  Kiyoshi Ichimoto 《Solar physics》2010,266(1):5-16

We performed two-dimensional spectroscopic observations of the preceding sunspot of NOAA 10905 located off disk center (S8 E36, μ≈0.81) by using the Interferometric BI-dimensional Spectrometer (IBIS) operated at the Dunn Solar Telescope (DST) of the National Solar Observatory, New Mexico. The magnetically insensitive Fe I line at 709.04 nm was scanned in wavelength repetitively at an interval of 37 s to calculate sequences of maps of the line-wing and line-core intensity, and the line-of-sight Doppler velocity at different line depths (3% to 80%). Visual inspection of movies based on speckle reconstructions computed from simultaneous broadband data and the local continuum intensity at 709.04 nm revealed an umbral dot (UD) intruding rapidly from the umbral boundary to the center of the umbra. The apparent motion of this object was particularly fast (1.3 km s⁻¹) when compared to typical UDs. The lifetime and size of the UD was 8.7 min and 240 km, respectively. The rapid UD was visible even in the line-core intensity map of Fe I 709.04 nm and was accompanied by a persistent blueshift of about 0.06 km s⁻¹.  相似文献